Synthesis of 4-substitutedimino-4H-benzo[d][1,3]thiazin-2-amines via palladium-catalysed isocyanide insertion in 2-bromophenylthioureas

Pandey, Garima; Bhowmik, Subhendu; Batra, Sanjay

dc.contributor.author	Pandey, Garima
dc.contributor.author	Bhowmik, Subhendu
dc.contributor.author	Batra, Sanjay
dc.date.accessioned	2017-05-30T11:36:44Z
dc.date.available	2017-05-30T11:36:44Z
dc.date.issued	2014
dc.identifier.citation	RSC Advances, 2014, 4, 41433–41436	en
dc.identifier.uri	http://hdl.handle.net/123456789/1694
dc.description.abstract	The palladium-catalysed isocyanide insertion in 2-bromophenylthioureas results into the formation of 4-substitutedimino-4H-benzo[d][1,3]thiazin-2-amines via C-S cross coupling reaction of the intermediate imidoylpalladium species. The investigations into the substrate scope revealed that whereas reactions of cyclohexyl isocyanide were successful with aromatic as well as aliphatic thioureas, reactions of all other isocyanides (except ethyl 2-isocyanoacetate) were successful with aromatic thioureas only.	en
dc.format.extent	214739 bytes
dc.format.mimetype	application/pdf
dc.language.iso	en	en
dc.relation.ispartofseries	CSIR-CDRI Communication no 8769	en
dc.subject	Pandey	en
dc.subject	Garima	en
dc.subject	Bhowmik	en
dc.subject	Subhendu	en
dc.subject	Batra	en
dc.subject	Sanjay	en
dc.title	Synthesis of 4-substitutedimino-4H-benzo[d][1,3]thiazin-2-amines via palladium-catalysed isocyanide insertion in 2-bromophenylthioureas	en
dc.type	Article	en