Synthesis, 1H NMR and X-ray crystallographic studies of three isomeric butylidene linker protophanes

Avasthi, Kamlakar; Shukla, Lakshmi; Kant, Ruchir

dc.contributor.author	Avasthi, Kamlakar
dc.contributor.author	Shukla, Lakshmi
dc.contributor.author	Kant, Ruchir
dc.date.accessioned	2015-06-05T05:21:51Z
dc.date.available	2015-06-05T05:21:51Z
dc.date.issued	2014
dc.identifier.citation	Chemistry & Biology Interface, 2014, 4(5), 292-300	en
dc.identifier.uri	http://hdl.handle.net/123456789/1550
dc.description.abstract	In this study, the synthesis of isomeric butylidene linker protophanes by the reaction of butylidene linker bis-lactam with n-propyl iodide in K2CO3/DMF is reported. All the three isomers showed folded (syn) conformation in solution based on 1H NMR analysis. More importantly, this folding carries over to the solid state due to intramolecular ππ interactions as revealed by single crystal X-ray crystallography.	en
dc.format.extent	402447 bytes
dc.format.mimetype	application/pdf
dc.language.iso	en	en
dc.relation.ispartofseries	CSIR-CDRI Communication No. 8848	en
dc.subject	Arene Interactions	en
dc.subject	Butylidene linker	en
dc.subject	Protophanes	en
dc.subject	Pyrazolo[3,4-d]pyrimidine	en
dc.title	Synthesis, 1H NMR and X-ray crystallographic studies of three isomeric butylidene linker protophanes	en
dc.type	Article	en