IodoMeyer-Schuster Rearrangement of 3-Alkoxy-2-yn-1-ols for  β-Mono(Exclusively Z-Selective)-/di-Substituted α-Iodo-α,β-Unsaturated Esters

Puri, Surendra; Thirupathi, Nuligonda; Reddy, M S

dc.contributor.author	Puri, Surendra
dc.contributor.author	Thirupathi, Nuligonda
dc.contributor.author	Reddy, M S
dc.date.accessioned	2015-05-08T06:18:22Z
dc.date.available	2015-05-08T06:18:22Z
dc.date.issued	2014
dc.identifier.citation	Organic Letters, 2014, 16(20), 5246-9	en
dc.identifier.uri	http://hdl.handle.net/123456789/1446
dc.description.abstract	We herein present the iodo Meyer-Schuster rearrangement of 3-alkoxypropargyl alcohols for α-Iodo-α,β-unsaturated esters using iodine or NIS in dichloromethane at ambient temperature. Substrates prepared from both aldehydes and ketones are found to be equally good feedstock for the reaction to produce β-mono- and -disubstituted products. Irrespective of the substitution, substrates prepared from aldehydes gave Z-isomers exclusively	en
dc.format.extent	457297 bytes
dc.format.mimetype	application/pdf
dc.language.iso	en	en
dc.relation.ispartofseries	CSIR-CDRI Communication No. 8800	en
dc.subject	IodoMeyer-Schuster	en
dc.subject	β-Unsaturated Esters	en
dc.title	IodoMeyer-Schuster Rearrangement of 3-Alkoxy-2-yn-1-ols for β-Mono(Exclusively Z-Selective)-/di-Substituted α-Iodo-α,β-Unsaturated Esters	en
dc.type	Article	en