dc.contributor.author |
Chakraborty, T K |
|
dc.contributor.author |
Pulukuri, K K |
|
dc.contributor.author |
Sreekanth, Midde |
|
dc.date.accessioned |
2014-07-21T10:37:41Z |
|
dc.date.available |
2014-07-21T10:37:41Z |
|
dc.date.issued |
2010 |
|
dc.identifier.citation |
Tetrahedron Letters 2010, 51(49), 6444 – 6446 |
en |
dc.identifier.uri |
http://hdl.handle.net/123456789/1312 |
|
dc.description.abstract |
A stereoselective synthesis of the C1-C15 fragment of a G-actin binding natural macrodiolide, rhizopodin was achieved using, as key steps, highly stereoselective acetate aldol reactions to build the C1-C7 fragment, one pot oxazole synthesis and an asymmetric Keck allylation reaction to build the C8-C15 fragment and finally, a Stille reaction to couple both the fragments. |
en |
dc.format.extent |
163015 bytes |
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dc.format.mimetype |
application/pdf |
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dc.language.iso |
en |
en |
dc.relation.ispartofseries |
CSIR-CDRI Communication No. 7964 |
en |
dc.subject |
Rhizopodin |
en |
dc.subject |
Acetate aldol reaction |
en |
dc.subject |
Keck allylation |
en |
dc.subject |
Stille coupling |
en |
dc.title |
Studies directed towards the synthesis rhizopodin: stereoselective synthesis of the C1-C15 fragment |
en |
dc.type |
Article |
en |