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| Title: | Stereoselective synthesis of homoallyl nitroalkane derivatives via base-promoted regioselective decarboxylation in Baylis-Hillman derivatives |
| Authors: | Nayak, Maloy
Batra, Sanjay |
| Keywords: | Homoallyl nitroalkane
regioselective
Baylis-Hillman
decarboxylation
bis-allylnitroalkane |
| Issue Date: | 2009 |
| Citation: | Eur. J. Org. Chem. 2009, 3505–3507 |
| Series/Report no.: | CDRI Communication Number 7756 |
| Abstract: | The regioselective decarboxylation during the saponification of the nitroalkanoates synthesized from the Baylis-Hillman acetates of acrylates to stereoselectively afford homoallyl nitroalkane is described. In contrast the similar nitroalkanoates derived from the Baylis-Hillman acetates of acrylonitrile gave bis allyl nitroalkanes. |
| URI: | http://hdl.handle.net/123456789/525 |
| Appears in Collections: | Medicinal and Process Chemistry
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| sbatra-7756-EJOC-2009-3505.pdf | | 105Kb | Adobe PDF | View/Open |
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