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| Title: | An expeditious protocol for sesquiterpene-cored functionalized arenes from S-(-)-citronellal |
| Authors: | Goel, Atul
Verma, Deepti |
| Keywords: | Bisabolene
sesquiterpene
2H-pyran-2-ones
citronellal
ring transformation approach |
| Issue Date: | 2009 |
| Citation: | Tetrahedron Lett (2009) 50, 2086-2089 |
| Series/Report no.: | CDRI Communication No. 7364 |
| Abstract: | An expeditious straightforward synthesis of sesquiterpene-cored arenes functionalized with electron-withdrawing or donating substituents is described and illustrated by Michael addition of S-(-)-citronellal on functionalized 2H-pyran-2-one in a single step at room temperature. The reaction was further generalized by synthesizing isoprenylated 9,10-dihydrophenanthrene-2-carbonitrile using 5,6-dihydro-2-oxo-4-sec-amino-2H-benzo[h]chromene-3-carbonitriles and S-(-)-citronellal under similar reaction conditions. |
| URI: | http://hdl.handle.net/123456789/478 |
| Appears in Collections: | Medicinal and Process Chemistry
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| Tetrahedron Lett. 2009, 50, 2086-2089.pdf | | 150Kb | Adobe PDF | View/Open |
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