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| Title: | Ti(III)-Mediated Radical Cyclization of β-Aminoacrylate Containing Epoxy Alcohol Moieties: Synthesis of Highly Substituted Azacycles |
| Authors: | Chakraborty, Tushar Kanti
Samanta, Rajarshi
Roy, Saumya
Balasubramanian, Sridhar |
| Keywords: | Piperidine
pyrrolidine
indolizidine
Ti(III)-mediated epoxide opening
radical cyclization
β-aminoacrylates |
| Issue Date: | 2009 |
| Citation: | Tetrahedron Letters,50,3306–3310 (2009) |
| Series/Report no.: | CDRI Communication No.7694 |
| Abstract: | Ti(III)-mediated radical cyclization of β-aminoacrylate containing 2,3-epoxy alcohol moieties led to the formation of highly substituted piperidine and pyrrolidine rings. The pyrrolidine ring system was then transformed into an indolizidine framework present in many natural products. |
| URI: | http://hdl.handle.net/123456789/442 |
| Appears in Collections: | Medicinal and Process Chemistry
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| tkchakraborty-7694-2009-tetlett-50-3306.pdf | | 267Kb | Adobe PDF | View/Open |
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